==> it is once we have chosen a white card what colour will the opposite side be.
Yes, and the reason that the answer is white 2/3 of the time is because you're going to asking that question twice as often when holding the white/white card than you would be when holding the red/white card. Therefore, twice as often, you're going to see a white background.
You're going to pick the white/white card the same number of times that you're going to pick the red/white card. Agreed?
Let's say you pick each card 100 times. In all 100 picks of the white/white card, you're going to then ask the question about the opposite side. But you're only going to ask that question 50 times from the 100 picks of the red/white card because half the time, it will come up red, and you're not going to ask the opposite question in those cases.
So you're going to ask the opposite side question 150 times: 100 times from picking the white/white card and 50 times from picking the white side of the red/white card. You'll see the opposite side be white 100 times and be red 50 times. That's a 2/3 of the opposite being white and and 1/3 chance of the opposite being red. And that's after having chosen a white card.
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