Is the folder named Programs, Program, or Program Files? If it's Program or Programs and NOT Program Files is this folder in the root directory under C: and what's in that folder. If it's in the root directory then you need to if possible either move it out of the root or rename it to something else. Try that and see if that keeps it from appearing at startup.
Try to disable one program at a time from the startup in MSCONFIG. Probably, there is one program, somehow refering to the folder , which cannot start.
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