I believe you can accomplish this by embedding an ICC profile. I think you have to change your color settings in the preferences and then when you save make sure to check the box that says embed the color profile. I've never done this b4 but I think that is what you want to do.
Do a google search for [ICC Color Profile + Adobe Photoshop]
I don't think this is as easy as it sounds. Only two ways to work with spot colors in photoshop: Duotone & adding spot channels to other color modes. So far, so good. Now throw transparency into the mix, and suddenly you have a file that's nearly impossible to import reliably into any application other than Photoshop.
Both Illustrator and InDesign can import PSD files, but only if they're in standard color modes. Anything else, and you'll have to figure out some kind of workaround, like clipping paths, or coloring grayscale images in the layout application. Failing that, you'll have to convert to process.
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