The HSG80 uses something called "Selective Storage Presentation" (SSP) to control server access (actually HBA access) to individual LUN's. Look at the ACCESS field on the LUN and the names in the connection table ("sho conn"

the entries in the connection table correspond to the WWID's of the HBA's in your servers.
If you want to move from 36GB to 72GB, you have a choice:-
If you have enough room for both sets of drives, add the new drives, create the storage set and the LUN, present to your server. Then to an IO rescan (i dont know how that is done with Netware, a reboot usually does it) and then format the new LUN and copy your data from the old to the new LUN. dismount the old LUN and the job is done.
Or the alternative is to backup your data, remove the old LUN and its disks, replace with the bigger disks and recreate the LUN, then Restore your data, sounds simple but it usually takes a lot lot longer, and your system is unavailable while you do it!