Another thing to remember about the NEC is that is has nothing to do with installing a workable electrical installation. It's only goal is safety, read the beginning of the NEC and they tell you that even if you install everything according to code, it doesnt mean that the system will work reliably, it only means it will not cause any harm to people. SO, the separation issue between line voltage and low voltage may only require a minimum distance by code, but that only insures safety.
At least one typical lighting installation we do requires CAT5 cable looped between all the electrical switches, then you replace a regular electrical switch with an addressable switch which is connected to a CAT5 wired backbone running RS-422. I met with my electrical inspector/instructor and said how do i make this work?
What he came up with was basically to meet Cat5 requirements, the wire had to have a 300 volt rating on the jacket. Since that jacket rating was twice the operating voltage in the box (120 volts) the two wires could co-exist in the same box with a 1/4" seperation. It's been a few years since we went through this, so I hope my memory is accurate, but what we ended up with was CAT5 wire in the same box, entering at the top while the 120volt romex entered from the bottom of the box, and maintaining a 1/4" separation.
Anyway, too much information, but just keep in mind that the NEC is only a code concerned with safety, not function of the electrical system.
Good Luck! It is only my opinion, based on my experience and education...I am always willing to learn, educate me!
Daron J. Wilson, RCDD
daron.wilson@lhmorris.com