There is a tool, in SBS that sets it all up for you, however. The answer is no, there will be no problem with the different names, just make sure you set up your recipient policy.
There is no relationship between your SMTP domain and AD domain unless you set one up. The SMTP domain is handled by the Recipient Policy in Exchange, and can be whatever you want it to be.
Pat Richard, MCSE MCSA:Messaging CNA
Want to know how email works? Read for yourself -
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