No, you can't expect VFP to open a binary word processor file and print it, you rather make that a job for Windows.
Shellexecute with action "print" would print any file the way the standard application the OS knowss associated with the file extension does.
The other point If you automaate Open Office, then there should not only be a way to create and save, but also print files via that automation. If you don't know, Intellisense in the command window could tell you.
Chriss