Usernames aren't tied to Machines name unless you specified the only allow to logon to permission.
The only real way to gleen what you're asking here noting the exception above is to turn on auditing to the level which records both the username and machine name.
There is an easy way to do this if you are running Symantec Antivirus on your network. Use the Symantec System Center Console and it will list the computer name, username, and IP address leased by that computer. If you arent running Symantec I am sure the other antivirus aps have something similar.
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