To stop people mapping persistent drives, you could put a couple of lines into your login script like:
net use /persistent:no
net use * /delete /y
To stop people actually using the Net Use command (as I think you mean), you really need to start playing with the group policy (although in a noisy office with a huge pile of paperwork in front of me at the moment, I'm struggling to think where... :/). That or disable the Run command and access to the Command Prompt, but this may stop other required programs from being run.
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