I use AOL v6.0 and have tested it with IE v5.2 and Netscape v4.72 and v6.0, AOL installs IE as it's browser on setup. AOL has owned Netscape for some time now, so AOL should work semelessly with both browsers.
To answer the question, you need to minimize AOL to use the Netscape browser, you do not need to start IE, AOL automatically opens it when you type a URL in the Address window.
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