Try going to the Exchange System Manager -> Servers -> yourservername -> Protocols -> SMTP -> Default SMTP Virtual Server -> Properties -> General -> Advanced -> Edit.
There you can change your port number, alternatively you can set up an additional SMTP Virtual Server and let all the mail flow...
You can create a catch-all by creating a sink event: HOW TO: Create a "Catchall" Mailbox Sink for Exchange 2000 (Q324021) http://support.microsoft.com/default.aspx?scid=kb;en-us;Q324021&SD=MSKB
Steven
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