This works
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[HKEY_CURRENT_USER\Software\Microsoft\Office\10.0\Outlook\Security]
"Level1Remove"=".exe;.com;.url;.bat"
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Add any other extensions you also want access too.
The problem may not relate to Word but to a adware blocker. I have tweeak xp pop up blocker installed on my pc and as I type certain addresses it closes the window as I get to the .com eg www.whitepages.com.au it would close the window as I type the m on the com.
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