Forgot about the defualt gateway option on the VPN connection.
Looks like you have that checked, so most of your traffic should be going across the VPN. You should not be able to connect to any host anywhere on the internet (except those that are on your internet subnet as determined by your ISP). That in itself is not a problem if that is the behavior that you want, and there are some good reasons to do that. Just kinda forgot that you might be configured that way. Again not a problem, but that is why you don't have a line like the one I described earlier.
Based upon what I see in your routing table, I think the Realtek ethernet adapter might be causing some problems. Even though it is not active, there is a routing entry pointing to is (last line before the default gateway, referencing interface 2). Worth a try, as all looks well otherwise. Goto your Network and Dialup Connections folder, right-click on the connection associated with that adapter and select 'Disable'. Restart your machine and try again.
If that doesn't help, disconnect from the VPN, unmark the box that says 'Use default gateway on remote network' (Connection properties, networking tab, highlight TCP/IP and click properties, then advanced.) Try the connection again and see what happens.