C# seems to be set, but you could also choose VB.NET. I don't say so because they are essentially interchangable, because both end up being compiled into the same bytecode (MSIL), but there are more than just syntax differences and C# is having an edge over VB.NET. But it's not only the curly brackets that offset some people from programming C,C++, C# or also JAVA and JavaScript, one thing you will surely stumble over is c# being case sensitive. Les Pinter pointed out he chose VB.NET for just these syntactical similarity to VFP. If you're interested Kevin NcNeish's book has a chapter about C# and VB.NET to point out the differences.
Since you'll mainly use .NET framework classes, they are classes with methods and their parmeterization, which means very similar usage, if you'd program the same usage of .NET framework in C# and VB.NET they will be very similar aside from curly brackets vs keywords, so that's a personal taste decision in that regard.
The major mindset change you have to go through is that both langauges are forcing you into the object oriented approach and don't be tempted to go F# as it's functional programming, that's a world apart from what procedural programming is.
I think many went to C# as it was the major language developed for .NET, it's C++ syntax but compares more to JAVA than being a C/C++ successor. The C++ successsor really is C++ in it's own roadmap, and in some aspects going there would be sticking to the same old Win32 with Windows API involved instead of .NET framework, but that also makes it not .NET, just a language also supported within the VS and it's clearly marked as leaving the core aspect of .NET by the term unmanaged code. It's not that it's bad to be unmanaged, it just means it actually compiles into assembly and not just some MSIL bytecode that is run by a CLR runtime. The idea of "managed" is about separating you from the dangers of pointers and such pitfalls of C programming, whereas C++ also has developes means to keep you from these pitfalls before .NET was invented.
Chriss