If the server is in the DMZ, then the main thing you'll need to do is tell your clients how to get to the machine in the DMZ. Depending on how your firewall is configured, just having the inside interface's IP address as your default gateway should do the trick. However, I've had situations where that was not adequate. If you're unable to reach the machine this may be the case. Remedy with a route statement.
example environment:
inside subnet: 10.0.1.0/24
inside firewall interface IP: 10.0.1.1
dmz subnet: 10.0.2.0/24
example command: (Win32 machines)
route add 10.0.2.0 mask 255.255.255.0 10.0.1.1
There's also the possibility that your DMZ does not trust your inside interface. In which case you will have to poke a hole through from your inside interface to to DMZ for the RDP port 3389 (TCP). Also, make sure none of your PCs built in firewalls are blocking this communication.