Not really. You should be coming from the same A1 IP for both. SM won't have a fun time seeing your SIP from 1 IP and your PPM from another.
So, how do you have that all setup?
On 8.1, you can use the "listen domain" of reverse proxies to pick where the traffic goes.
So, I have all my FQDNs for AMM, AADS, Presence, etc on 1 IP and the reverse proxies have listen domain "aads.kyle.com" and if it hears
on port 443, then the AADS proxy sends it to AADS and so on and so forth.
Maybe I haven't played around with the SIP phones to force the issue, but I find they always ask for PPM on a IP address. IX Workplace will ask via a FQDN.
In the reverse proxies, if I use "listen domain" for a bunch, if I add another with no listen domain - like for PPM - because hardphones are asking on a IP and you can't put a IP in there, then that reverse proxy overrides the rest, so I can't use PPM and all other UC with 1 IP.
So I use 1 IP for SIP/PPM, 1 for everything else. That's for data center 1 to get you to your primary SM. Repeat with 2 more IPs at data center 2 for your secondary.
So what's your DNS probe doing? Something like "sip-primary.lab.com" and directing it to a primary public IP if it's answering and otherwise directing to a second public IP? That's what I'd do for data center failover for anything UC but not for the SMs at least insofar as how I'm understanding it.