I should have said I am running XP Pro, 32 bit, not as a server.
That said, after reading a number of the links with a lot of conflicting advice, it seems the general consensus is "Don't do it".
I had thought of Cloning the drive (array) to a larger single drive (1 of 2), removing both of the old drives and installing both of the new drives with the clone already resized with Partition Magic. At least this way, I will have both of my original drives in perfect condition to recover from letting the smoke out.
I learned a lot following the links.
Thanks to everyone.
NARSBARS