Your working directory path is wrong, get rid of the winword.exe. The path is then correct, but whether this will work or not is uncertain. I am having similar problems, I get a little further in that the application opens but then complains about the file.
Make sure to use quotes around each path. Example "C:\program files\office\winword" "C:\docs\word.doc"
The space in files/folders such as program files would cause it to think you are showing two strings.
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