I don't know about printing from the design view, but have you tried the Tools -> Analyze -> Documenter. Perhaps that will give you the information you need. (FYI - This is the menu selection in Access 2000, but I don't think it would have changed VERY much).
As far as I know there is not a way to print the table structure from design view. If print screen will not work then you can take a look at the documenter. It is located in Tools\analyze\documenter.
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