I thought a little more about what you are asking and realize that you might be confused as to how ZEN works.
Associating an application to either a workstation or a user will not automatically install it. There are Numerous options that determine the behavior of the installation.
Generally you assoicate the application with a user, and then you check the boxes to determine where the icon will appear (if at all).. It can be the desktop, the quicklaunch, the taskbar, the startmenu, or the nal app window. That's the first step. For complex applications that require an installation, the idea is to install the application the first time you click the icon. The subsequent launches of the app will recognize that the app is installed and will just run it instead. (these are very general statements).
There is an option available that will 'force run' the app, causing it to launch the app and install it automatically. And many options can be used together to achieve different results.
Also, don't forget that you must have the ZEN agent installed on a workstation for it to provide the application launching service. The documentation you are reading probably assumes you know this. If you've installed all the ZEN components, you can find the agent at SYS

UBLIC\ZENWORKS\ZFDAGENT\ENGLISH\... something like that. and it's called ZFDAGENT.MSI.
One of the best things you could do is just go through ConsoleOne and open an App object and go through each tab and see what options are available. Most of them are pretty self explanitory.
Hopefully this will give you a place to start. And if you want to see a fat guy on a waterfall, go here
. But you can also find out some other good stuff about ZEN and what it can do for you since ZENworks is the focus of the fall issue..
Marvin