If your VG contains a DB or many large size of data,
I suggest you use exportvg/importvg, because
1.you want to MOVE not copy data to another server.
2.NFS is slow, limited by your network speed and traffic.
3.If you copy from NFS, permission of files will be changed, It may be a problem to you.
4.use exportvg/importvg is fastest way to move data.
Producdure is:
On serverA
1.umount ALL filesystem of this VG, to make all LV are closed.
2.varyoffvg VG
3.exportvg VG
4.rmdev -dl hdiskX (which VG resident)
5.power off external disk, unplug SCSI cable from serverA to serverB.
On serverB
6.cfgmgr
7.lspv to see which disk new added
8.importvg -y VG hdiskX (new disk)
9.mount ALL filesystem you need.
10.Change Characteristics of VG and filesystems to you want.
OK !
All time you need is less than 15 minutes! unless your have a very big disk.