As markdmac will tell you, "you can do just about anything with VB Script".
Microsoft has an excellent library of pre-written VB scripts at your disposal. If you run it on a regular basis as a task, you should get what you want. Here's an example from the script center i found in less than a minute. Cut and paste it with what you need for sending an email (no doubt an example exists for this too)
You could set an Alert to monitor free disk space in the "Performance" mmc. Add the logical disk counters and it will monitor and alert you through net send or email( using blat or somethimg similar).
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