Modify the parent key \9.0\ for office 2000. Otherwise, \8.0\ for office 97, \10.0\ for office 2002 accordingly.
It may well be the reg_binary controlling the settings be corrupted. Close word. Delete (manually or by .reg above) and re-launch word. Let it rebuild the key. If anything gone wrong, you'll always have your exported .reg stand ready to repair.
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