When you start up windows, if it is running 64-bit it will say Windows XP 64-bit Edition.
If your system is already started, right click on "My Computer", select Properties. Under System, it will tell you whether or not it is the 64 bit edition.
Alternatively, pop up a cmd prompt and type set. If you see ProgramFiles(x86) it is 64 bit.
Do not expect Windows XP 64 bit edition to run any any laptop.
That is something you only wish to your worst enemies.
Depending on the BIOS CPU-enablements and capabilities, the system could be 64 bit capable, as the CPU is created for it, but if it older then a few months, don't bother, get a new laptop.
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