You need to select the subject from the background.
There are many ways to do that, you could try a threshold, you could select with the lasso tool or you could use a quickmask and brush/eraser.
A threshold will give you black and white directly but with a selection you could simply fill the selection with black and invert the selection before filling with white (or whatever combinations you prefer.
If the edges are a litte ragged you could soften them with a mild blur.
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