Distance - 328 (100 meters) feet total for the Cat5 ethernet link, the distance of 300 feet (90 meters) is to allow for patch cables at each end.
Cat5e or E - there is NO standard for big E or little e, the EIA/TIA standard defines Cat5e to a particular set of parameters, the overall bandwidth being 100 MHz. What we are finding in the field though is Cat5e "minimally compliant" at 100 Mhz, and Cat5e "hyper" or "extreme" or "insert manufacturer's label here" for a Cat5e cable that has a higher bandwidth (such as 250 or 350 Mhz). Using the higher bandwidth cable in theory gives you more headroom for higher bandwidth should you choose to use it. Currently, that next step would be gigabit ethernet for example. We almost always use the better product, it's not much more money and seems to be prudent.
Collisions - the network topology and hardware is more of an issue for collisions than the media. Either Cat5e or Fiber in this situation could give you 100 mbs full duplex depending on the hardware. Collisions are a 'feature' of ethernet technology, and minimal collisions are to be expected.
If you have a switch at each end with a 100 mbs full duplex connection, and you use Cat5e you should get the full channel bandwidth. Interestingly, if you use fiber you will get the same throughput. If you are building for future growth, then gigabit fiber would be a good choice.
Hope that helps, Good Luck!
It is only my opinion, based on my experience and education...I am always willing to learn, educate me!
Daron J. Wilson, RCDD
daron.wilson@lhmorris.com