Make sure that you are not resizing the images in Dreamweaver (if you have their sizes will be in bold on the properties inspector - to reset them click on "W" and "H" next to the values). This results in the cheapest, nastiest looking images around because it is not an image resizer (and neither is a browser). Make sure that the exported image is the size that you want it to be on the page. It only needs to be tweaked a pixel to look shite.
Flat, blocks of colour, transparencies and "cartoon-esque" artwork should be a gif, and leave photos and gradients to jpeg compression. However, always use the previews and tweak the image according to the use you require.
As deecee mentioned, if you are using transparent images, make sure the background colour which you are removing for the image is the colour of the background which you are going to be placing the finished product. This will ensure that the egdes of the image anti-alias to the right colour and don't result in the cheap (and frankly should be illegal) halo effect around images. Derren
[Mediocre talent - spread really thin]