/devices as far as I can remember has been an vital part of the OS
well I guess we can go back one step.
/dev, the contents of this directory are all symbolic links to /devices.
lets say your machine had a /dev/dsk/c3t3d0s2 in /dev. you would know that by doing a ls -la on /dev.
you would then see that it points back to /devices.
I was always told that
/dev = the logical device path to any give device
and
/devices = the physical device path to any given device.
There have been many times that I have had to remove the logical entries of a devices and had the system regenerate them again. I have done this a lot with tape drives.
ls -l1 /dev/dsk/c3t3d0s2
lrwxrwxrwx 1 root root 61 Jul 19 17:50 /dev/dsk/c3t3d0s2 -> ../../devices/pci@0,0/pci1022,7458@11/pci1000,3060@4/sd@3,0:c