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MultiBootISOs Works by utilizing a Syslinux Bootloader chainloaded to GRUB4DOS.
Even if the motherboard supports USB booting, its implementation may be defective, results and direct observation lead to find that there are motherboards with one or more of the following “defects”:
1. motherboards that do not boot from USB when you switch the PC on, but do so after a warm boot (CTRL+ALT+DEL)
2. motherboards that do not boot from USB after a warm boot (CTRL+ALT+DEL), but do so when you switch the PC off then on (cold boot)
3. motherboards that sometime boot and sometime do not
4. motherboards that ONLY boot from USB media formatted as “Superfloppy” (a drive formatted as to have no MBR, but directly the BOOTSECTOR as Sector 0)
5. motherboards that ONLY boot from USB media formatted as “Hard Disk” (a drive that has a “normal” MBR and one or more partitions)
6. motherboards that only boot from a FAT 16 Primary partition (hex 06)
7. motherboards that only boot from a FAT 16 Primary partition (hex 06) or from a VFAT16 (or FAT 16 LBA mapped) Primary partition (hex 0e)
8. motherboards that can boot from Win 9x files but do not with NT/2K/XP/Server 2003 ones or FREEdos ones
9. motherboards that need a setting like "USB keyboard support from BIOS" enabled and some that need it disabled
10. motherboards that will only boot from the "special" ZIP disk like formatting
11. motherboards that will only boot from USB after having "Enabled" the "Reset Configuration Data" in the BIOS
A reasonable troubleshooting path is the following (if you are not lucky enough to get it at first try), I assume that you DID change the setting in BIOS as to boot from USB, didn't you?:
1. Jot down all current settings in the BIOS (so that you will later be able to restore them)
2. Load "Failsafe settings" in BIOS
3. Disable EVERYTHING you do not need for the test, such as Hard Disk(s), Floppy Disk(s), Audio, etc.
4. Try using a FAT16 (hex06) partition formatted USB key with a MBR (Hard Disk Simulation) and Windows 9x boot files
5. Try switching on and off the "USB keyboard support from BIOS" BIOS setting
6. Try with a Cold boot
7. Try with a Warm boot (CTRL+ALT+DEL)
8. Try after having "Enabled" the "Reset Configuration Data" in the BIOS
9. If you get as far as getting a message on the screen or the Windows 98 bootscreen, DO NOT give up, even if it hangs, as said there some "magic" factor involved, try a couple more times and most probably it will boot, it seems like there is some kind of "timing" problem
10. Loop to # e) after having formatted the key as "Superfloppy" (no MBR)
11. Loop to # e) after having formatted the key as "ZIP" (no MBR and special geometry)
Once you have established that the combination of USB key / motherboard works, you can try some other options, like formatting as VFAT 16 (hex 0e) or FAT/VFAT 32, respectively (hex 0B) or hex (0C), then as NTFS or whatever.