Yep.
1) Install Ethernet NIC's on both PC's.
2) Connect them up. If there are lights on the back of the NIC's check them. If they are lit, you have a link.
3) Go to the adapter configuration page and make sure the NIC (Network Interface Card) has TCP/IP and NETBIOS installed. (it may be called NETBEUI instead). Do this for each PC.
4) in the TCP/IP options for each card, set an address of 192.168.0.x (x=1-254) and a subnet mask of 255.255.255.0
Do NOT use DHCP/DNS/WINS as they will not help you! Also you should join your computer to a workgroup. You can do this from 'My Network Places' or 'Network Neighbbourhood'
5) Restart both PC's with their new settings
6) On each machine, test that TCP/IP is properly installed by typing <PING 127.0.0.1>. You should get 4 replies.
7) If that works, type <PING 192.168.0.x> (this should be the address of the OTHER machine) Again you should get 4 replies.
8) If that works

try <PING NAME> (where NAME is the NETBIOS name of the computer you are pinging) this time if you get a response you can consider yourself fully connected!!
If you would like a better explanation of any of the points here, or an explanation of how these things work let me know.
HTH
Tels Win2000 Network Administrator