By "structure," do you mean "node"? I tried doing a search for XMLDom structures and the results mostly came back discussing nodes.
Even then, I didn't really see an easy way to compare them, though.
Unfortunately it would probably be a lot easier to use something like XMLSpy. You could do it with Delphi, but if the structures are anything other than extremely simple, it will be an inordinate amount of programming - me thinks.
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