oop's the 'line 1' part of the command is new with version 6.3 if I remember correctly. Upgrading to 6.3 makes editing ACL's much easier.
Since you are using version 6.2, you'll need to copy the old list into notepad, edit it (add the new line in front of all the other commands), clear the old list on your pix and paste the modified list back.
you say you have an 'allow any' to the exchange server. Do you mean you allow any eq smtp and allow any eq pop3. If you have a plain 'permit ip any host exchange-server' then your machine is wide open to any hacking attempts.