Have to make some assumptions about your position.
It sounds like your new mail account is for a different domain name to your current one. In this case smah's response is quite correct - you'll have to get advice from the ISP on pretty much all of the configuration parameters.
If, however...
Further to archived thread thread605-867916 .
Periodically over the last few months I (and other Outlook users) receive "cannot connect" messages with error number 0x800ccc0e when trying to send via SMTP, despite the same configuration having worked quite happily for many weeks beforehand...
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